Chemical elements
  Boron
    Isotopes
    Energy
    Production
    Application
    Physical properties
    Chemical properties
      Boron Hydrides
      Tetraborodecahydride
      Borobutane
      Hexaborododecahydride
      Borohexylene
      Boron trihydride
      Boro-ethane
      Decaborotetradecahydride
      Boron halogen
      Boron trifluoride
      Hydrofluoboric acid
      Potassium borofluoride
      Fluoboric acid
      Perfluoboric acid
      Boron subchloride
      Boron trichloride
      Boron tribromide
      Boron tri-iodide
      Oxides of Boron
      Tetraboron trioxide
      Boron dioxide
      Tetraboron pentoxide
      Borohydrates
      Hypoborates
      Boron sesqui-oxide
      Boron trioxide
      Boric anhydride
      Boric Acids
      Orthoboric acid
      Boric acid
      Boracic acid
      Complex Boric Acids
      Perboric Acid and Perborates
      Sodium perborate
      Sodium hyperborate
      Potassium perborate
      Rubidium perborate
      Ammonium perborate
      Barium perborate
      Boron sesquisulphide
      Boron trisulphide
      Boron pentasulphide
      Boron selenide
      Boron nitride
      Boron amide
      Boron imide
      Boron phosphide
      Boron phospho-iodides
      Boron carbide
      Boron thiocyanate
      Boron Alkyls
      Boron trimethyl
      Boron Silicides and
      Boroethane

Borohydrates






When one part of boron sesqui-oxide is heated with 2¼ parts of magnesium powder for 45 minutes at a red heat in a rapid stream of hydrogen, the main products are magnesia and magnesium boride, Mg3B2:

6Mg + B2O3 = 3MgO + Mg3B2.

It appears to be essential to the success of the experiment that the mixture should gently deflagrate for about five minutes after the heating commences.

The crude mixture from the foregoing reaction evolves hydrogen when treated with water. It has been shown by Travers, Ray, and Gupta that the magnesium boride is decomposed as follows: -

Mg3B2 + 6H2O = Mg3B2(OH)6 + 3H2.

The product is an almost white powder, insoluble in water; it is the magnesium derivative of a compound B2(OH2)6, which, from analogy with the carbohydrates, may be termed a borohydrate.

The solution obtained by treating the boride with water is found to contain small quantities of substances which exhibit the remarkable property of evolving hydrogen, with brisk effervescence, when acidified. These substances are also borohydrates or allied compounds, and, like the hydroborons obtained from the magnesium boride by the action of acids, appear to be the products of certain unknown side reactions. The amounts of these substances obtained are very small in comparison with the amount of boride required for their production.

The solution is usually yellow, owing to the presence of colloidal boron. It decomposes slowly at the ordinary temperature, hydrogen being evolved. In the presence of platinum black the rate of decomposition is greatly accelerated. The solution precipitates silver and mercury from their salts immediately; with copper salts either copper hydride or amorphous boron appears to be precipitated, according to circumstances. When acidified, the solution evolves hydrogen; the liquid thus obtained decolorises iodine.

A careful, quantitative study of the properties of the solution has led Travers, Ray, and Gupta to the conclusion that the solution contains two substances of the formulae H6B2O2 and H6B2O3Mg, the latter being the magnesium derivative of a compound H8B2O3. It is suggested that in these compounds boron has a valency of five; and if, as seems highly probable, the evolution of hydrogen takes place by the elimination of pairs of hydrogen atoms attached to adjacent boron atoms, the properties of these compounds can be explained by assigning to them the formulae: -

and

The products formed on treatment with acid arise in the following manner: -

(i) = +2H2

(ii) = = = + H2

The compound ho.b: b.oh, which is analogous to hyponitrous acid in its structure, and the compound bh3: b(oh)3 are oxidised by iodine to boron dioxide, B2O2: -

(iii) + I2 = + 3HI

(iv) + 2I2 = + 4HI + H2O

When the solution obtained by the action of water on magnesium boride is treated with ammonia, magnesium hydroxide is precipitated. In the conversion of the magnesium derivative H6B2O3Mg into the ammonium compound, however, intra-molecular change apparently occurs, thus: -

HB(OH)3:HBH3H2B(OH)2:H2BH(OH)

for the new product, when acidified, evolves twice as much hydrogen as the initial: -

H2B(OH)2.H3BH(OH) = B(OH)2.BH(OH)

yielding a product which is oxidised by iodine to boron dioxide, B2O2: -

B(OH)2.BH(OH) + I2 = B:O.B:O + 2HI + H2O

The magnesium derivative Mg3B2(OH)6, already mentioned, undergoes decomposition when treated with strong ammonia in an atmosphere of hydrogen. Travers and Ray, who have investigated the reaction, conclude that the soluble product of the change is a di-ammonium derivative of the compound -

BH2(OH)2.BH(OH):BH(OH).BH2(OH)2.

When acidified, this compound loses hydrogen, thus: -

BH2(OH)2.BH(OH):BH(OH).BH2(OH)2 = 2H2 + BH(OH)2:B(OH):B(OH):BH(OH)2,

and the new product loses more hydrogen when treated with iodine: -

BH(OH)2:B(OH):B(OH):BH(OH)2 + I2 = 2HI + B(OH)2.B(OH).B(OH).B(OH)2.

By evaporating the ammoniacal solution in vacuo and heating the residue, the oxide B4O5 is obtained, thus: -

BP2(OH)2.BH(OH).BH(OH).BH2(OH2) + 2NH3 = + 5H2 + H2O + 2NH3


© Copyright 2008-2012 by atomistry.com